In a medium saucepan over medium heat, combine white sugar, brown sugar, and butter. Heat and stir until the butter is melted. Take off heat and add chocolate chips. Stir until all melted together. Place in the fridge to cool slightly until read to mix with the rest of the ingredients (Don’t forget and leave it in there or the butter will get hard. This is just to help cool it down.)
In a large mixing bowl beat the eggs for one minute. Next, mix in the vanilla. Add in the potato flake starter and mix together. It can be a recently fed starter, or a starter that has been sitting in the fridge.
Add in the cocoa powder. Whisk to combine.
Make sure the butter mixture is not hot. If it is warm, that is okay. Mix with the egg mixture until just combined.
Add in the flour and only mix until you do not see any more white. Stop as soon as it is incorporated.
Cover with plastic wrap and place in the fridge for at least 10 hours, up to 24 hours for a long fermentation of the grains. If you want to jump start the fermentation before placing it in the fridge, leave the batter out at room tempature for a few hours and then place it in the fridge to finish the fermentation.
If you do not want to long ferment your brownies, skip this step and jump right into the next step.
Prepare a 9×9 pan by lining the bottom with parchment paper and oiling the sides.
Pour the thick batter into the prepared 9x9 pan. If fermented, it becomes even thicker, this is okay! Do your best to spread the mixture out into an even layer.
Bake 40 minutes at 350℉ in the prepared 9 X9 pan. Set a timer for 35 minutes to check and see if the middle is set. When it is baked to your doneness preference, remove from the oven.
Allow to cool completely before slicing and serving. This will help it set up and keep them from falling apart as easily.